Fertiliser (Crop Nutrition)

The annual world trade in fertilisers in the mid-1990s amounted to approximately 120 million tonnes, which represented around 8% of all sea-borne bulk trade. The international fertiliser trade is a huge industry, which ranks fourth after coal, iron, and grain in terms of value.
The various steps involved in the manufacture of finished fertiliser products, from raw materials through intermediate products, are shown below.

AESSEAL plc have formed an alliance with a number of fertilizer manufactures with the common goal of reducing seal failures and increasing up time. Traditionally two main seal support methods are used in this industry when sealing slurries and or the chemicals associated with fertilizer manufacture, which within themselves have been identified as large volume water consumers whilst not providing the anticipated seal life. These two methods are indeed again the quench to drain method (API Plan 62), and the flush method (API Plan 32).

As previously discussed, these seal support methods have major limitations in normal process industries, however, using seals when pumping fertiliser constituents brings additional sealing challenges.

For example, Phosphoric Acid and pond water are less than desirable liquids to seal as compared to cold drinking water. Mechanical seal faces do not like heat nor do they like dirt and solids. When phosphoric acid is being sealed at normal process temperatures it does provide minimum lubricating qualities for the faces. The problem is that as the process changes so does the acid providing the film on which the mechanical seal faces run. If the acid gets too hot it will vaporise and when the temperature is too low the solids in the acid can come out of suspension. Both of these conditions will create adverse face conditions and greatly reduce the reliability needed to seal Phosphoric Acid.

Pond water is more difficult to seal than is Phosphoric Acid. Hot pond water is aggressive in nature, and due to its chemical make up it grows crystals that are very abrasive. Pond water does not provide the seal faces with any lubricating qualities, short or long term. Film stability is compromised here as well.

In the past, packing and single seals with high-pressure flushes have given the ability to run mechanical seals with a limited degree of success. The price paid for this success is shortened seal life, dilution of the acid strength, higher energy costs to drive off the water in the evaporation process and the continuous flow of water being added to the pond water system. All of these issues give way to higher plant operating costs.

The costs associated with water being added to the process are very high. The evaporation costs can be around £0.15 ($0.27/€0.22) per litre per hour (£0.55 / $1.00 / €0.83 per gallon per hour). Water to ground costs are very high as well. If the plant is in the liming process, the costs are considerably higher. Liming costs are somewhere around £1,611.11 ($2,900.00/€2,416.66) per year per litre per minute (per year per gallon per minute). There are two cost concerns here, one being the neutralisation of the pond water itself and the other being the loss of the Phosphoric Acid contained in the pond water. Plant costs and savings are easily seen here.

In this single application:

WATER SAVINGS
328,369,896 litres per year / 86,746,150 galls (US) per year

WATER COST SAVINGS
£1,154,737.20 per year / €1,732,105.00 per year / $2,078,527.00 per year

 

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